Boron structure evolution in magnetic Cr2O3 thin films

نویسندگان

چکیده

B substituting O in antiferromagnetic Cr2O3 is known to increase the Néel temperature, whereas actual dopant site and corresponding functionality remains unclear due complicated local structure. Herein, A combination of electron energy loss spectroscopy first-principles calculations were used unveil structures doped thin films. was found form either magnetic active BCr4 tetrahedra or various inactive BO3 triangles lattice, with σ∗ π∗ bonds exhibiting unique spectral features. Identification achieved by changing momentum transfer manipulate differential cross section for 1s-π* 1s-σ* transitions. Modeling experimental spectra as a linear simulated K edges reproduces π* / σ* ratios 15–42% occupying This result further supported based thermodynamic calculations.

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ژورنال

عنوان ژورنال: Materials Today Physics

سال: 2022

ISSN: ['2542-5293']

DOI: https://doi.org/10.1016/j.mtphys.2022.100753